| United States Patent Application |
20070080605
|
| Kind Code
|
A1
|
|
Chandrashekhar; MVS
;   et al.
|
April 12, 2007
|
Betavoltaic cell
Abstract
High aspect ratio micromachined structures in semiconductors are used to
improve power density in Betavoltaic cells by providing large surface
areas in a small volume. A radioactive beta-emitting material may be
placed within gaps between the structures to provide fuel for a cell. The
pillars may be formed of SiC. In one embodiment, SiC pillars are formed
of n-type SiC. P type dopant, such as boron is obtained by annealing a
borosilicate glass boron source formed on the SiC. The glass is then
removed. In further embodiments, a dopant may be implanted, coated by
glass, and then annealed. The doping results in shallow planar junctions
in SiC.
| Inventors: |
Chandrashekhar; MVS; (Ithaca, NY)
; Thomas; Christopher Ian; (Ithaca, NY)
; Spencer; Michael G.; (Ithaca, NY)
|
| Correspondence Name and Address:
|
SCHWEGMAN, LUNDBERG, WOESSNER & KLUTH, P.A.
P.O. BOX 2938
MINNEAPOLIS
MN
55402
US
|
| Serial No.:
|
509323 |
| Series Code:
|
11
|
| Filed:
|
August 24, 2006 |
| U.S. Current Class: |
310/303 |
| U.S. Class at Publication: |
310/303 |
| Intern'l Class: |
G21H 1/00 20060101 G21H001/00 |
Goverment Interests
GOVERNMENT FUNDING
[0002] The invention described herein was made with U.S. Government
support under Contract No W314P46-04-1-R002 awarded by Defense Advanced
Research Project Agency (DARPA). The United States Government has certain
rights in the invention.
Claims
1. A Betavoltaic cell comprising: a substrate; structures formed of
semiconductor having voids, wherein the structures comprise shallow p-n
junctions; and electrical contacts coupled to the p-n junctions.
2. The Betavoltaic cell of claim 1 and further comprising a beta radiation
source in the voids.
3. The Betavoltaic cell of claim 2 wherein the beta radiation source
comprises Ni-63 or tritium (H-3).
4. The Betavoltaic cell of claim 1 wherein the structures are formed of
high aspect ratio SiC or SiC.sup.4.
5. The Betavoltaic cell of claim 1 wherein the aspect ratio of the
structures is at least approximately 10:1.
6. The Betavoltaic cell of claim 1 wherein the structures comprise
pillars.
7. The Betavoltaic cell of claim 6 wherein the pillars are formed of n
doped semiconductor with a p doped exterior portion.
8. The Betavoltaic cell of claim 1 wherein the structures comprise pores.
9. A Betavoltaic cell comprising: a SiC substrate; high aspect ratio
pillars supported by the substrate having voids between the pillars;
shallow pn junctions formed on the pillars; cathode contacts formed on
the pillars; an anode contact formed on a back side of the substrate; and
a beta radiation fuel disposed in the voids.
10. A method of doping SiC comprising: forming a layer of dopant
containing glass on an SiC surface; annealing the dopant containing glass
to diffuse boron into the SiC; and removing the dopant containing glass.
11. The method of claim 10 wherein the glass comprises borosilicate glass.
12. The method of claim 11 wherein the layer of borosilicate glass is
formed by deposition or is spun onto the SiC.
13. The method of claim 11 wherein the layer of borosilicate glass is
formed by plasma enhanced chemical vapor deposition.
14. The method of claim 10 wherein the annealing temperature is between
approximately greater than 1300.degree. C. to approximately 1800.degree.
C.
15. The method of claim 10 wherein the annealing is performed in a vacuum.
16. The method of claim 10 wherein the borosilicate glass is removed by
immersion in hydrofluoric acid or plasma etch.
17. The method of claim 10 wherein the boron containing material comprises
a boron containing ceramic.
18. The method of claim 10 wherein the SiC surface comprises high aspect
ratio n-doped structures.
19. A method of doping SiC, the method comprising: implanting a dopant
into the SiC; depositing a glass protective layer onto the SiC; annealing
to activate the dopant; and removing the glass.
Description
RELATED APPLICATION
[0001] This application claims priority to U.S. Provisional Application
Ser. No. 60/711,139 (entitled BETAVOLTAIC CELL, filed Aug. 25, 2005)
which is incorporated herein by reference.
BACKGROUND
[0003] Modern society is experiencing an ever-increasing demand for energy
to power a vast array of electrical and mechanical devices. Since the
invention of the transistor, semiconductor devices that convert the
energy of nuclear particles or solar photons to electric current have
been investigated. Two dimensional planar diode structures have been used
for such conversion. However, such two dimensional structures exhibit a
number of inherent deficiencies that result in relatively low
energy-conversion efficiencies.
BRIEF DESCRIPTION OF THE DRAWINGS
[0004] FIGS. 1A, 1B, 1C, 1D and 1E illustrate steps involved in forming a
Betavoltaic cell according to an example embodiment.
[0005] FIG. 2 is an alternative structure for a Betavoltaic cell according
to an example embodiment.
[0006] FIG. 3 is a further alternative structure for a Betavoltaic cell
according to an example embodiment.
[0007] FIG. 4 is an illustration of the addition of fuel to a Betavoltaic
cell according to an example embodiment.
[0008] FIGS. 5A and 5B are diagrams illustrating the use of fluid fuel
according to an example embodiment.
[0009] FIGS. 6A, 6B and 6C illustrate the formation of a junction via
diffusion according to an example embodiment.
[0010] FIGS. 7A, 7B, 7C and 7D illustration the formation of a junction
via ion implantation according to an example embodiment.
DETAILED DESCRIPTION
[0011] In the following description, reference is made to the accompanying
drawings that form a part hereof, and in which is shown by way of
illustration specific embodiments which may be practiced. These
embodiments are described in sufficient detail to enable those skilled in
the art to practice the invention, and it is to be understood that other
embodiments may be utilized and that structural, logical and electrical
changes may be made without departing from the scope of the present
invention. The following description is, therefore, not to be taken in a
limited sense, and the scope of the present invention is defined by the
appended claims.
[0012] Three dimensional semiconductor based structures are used to
improve power density in betavoltaic cells by providing large surface
areas in a small volume. A radioactive emitting material may be placed on
and/or within gaps in the structures to provide fuel for a cell. The
characteristics of the structures, such as spacing and width of
protrusions may be determined by a self-absorption depth in the radiation
source and the penetration depth in the semiconductor respectively.
[0013] In one embodiment, the semiconductor comprises silicon carbide
(SiC), which is suitable for use in harsh conditions due to temperature
stability, high thermal conductivity, radiation hardness and good
electronic mobility. The wide bandgap of 4H hexagonal polytype (3.3 eV)
provides very low leakage currents.
[0014] In one embodiment, SiC pillars are formed of n-type SiC. P or n
type dopants may be formed on the pillars or any SiC structure in various
known manners. In one embodiment, p-type doping utilizes a borosilicate
glass boron source formed on the pillars. The borosilicate glass may then
be removed, such as by immersion in hydrofluoric acid followed by a
deionized water rinse or by plasma etch. Both substitutional and vacancy
mediated diffusion occurs. Other boron sources, such as boron nitride or
any other boron-containing ceramic may be used in place of the
borosilicate glass. The doping results in shallow planar p-n junctions in
sic.
[0015] The following text and figures describe one embodiment utilizing
high aspect ratio micromachined pillars in semiconductors. The formation
of PN junctions and provision of a radioactive beta-emitting material may
be placed within gaps between the pillars to provide fuel for a cell are
also described. A method for doping SiC is then described that utilizes
an easily removable sacrificial layer. Some example results and
calculations are then described.
[0016] FIGS. 1A, 1B, 1C, 1D and 1E illustrate formation of an example
betavoltaic cell. In one embodiment, a silicon carbide substrate 110 is
used. Other semiconductor substrates may be used if desired, such as
silicon. Photolithography and etching may be used to provide a structure
115 that has a larger surface area than a smooth substrate as shown in
FIG. 1B. In one embodiment, the structure 115 comprises etched pillars
120 separated by gaps 125 between the pillars. Standard plasma etching
techniques may be used to provide good control over sidewall profiles of
the etched pillars 120. The roughness of the sidewalls resulting from
electrochemical etching may provide traps for current flow.
Photolithography may be used to pattern high aspect ratio pillars,
yielding good control over the geometry of the device. This allows for
better optimization of power conversion efficiency, and also may lead to
better process control in commercialization.
[0017] To form the pillars in one embodiment, a semiconductor wafer is
patterned using standard photolithography techniques. The pattern is then
transferred using plasma etching techniques such as electron cyclotron
resonance (ECR) etching. These techniques can etch deep with good control
over the sidewall profile, allowing for the realization of high aspect
ratio structures.
[0018] Other structures may also be used such as stripes 210 in FIG. 2 and
scalloped stripes 310 in FIG. 3. In a further embodiment, pores in a
semiconductor substrate may formed with junctions to form a porous three
dimensional porous silicon diode having conformal junctions. Pore sizes
may range from less than 2 nm to greater than 50 nm. Just about any
structure that increases the surface area of the resulting battery may be
used, High aspect ratio structures that may be doped to provide shallow
junctions tend to provide the greatest increase in power density.
[0019] Using the high aspect ratio pillars to form shallow junctions may
lead to higher power densities over planar approaches. By etching through
a typical half millimeter thick wafer, using a Tritium radiation source,
this approach may yield power density increases of up to or more than 500
times planar or two dimensional approaches.
[0020] Either solid source or gas source diffusion may be used to diffuse
impurities 130 into the etched pillars 120, forming a p-n junction over
substantially the entire length of the pillar or surface of the
structure. Ohmic contacts 135, 140 compatible with the semiconductor,
such as aluminum are deposited as shown in FIG. 1D. In one embodiment,
contacts are formed on the tops of the pillars as indicated at 135, and
on the bottom side of the substrate as indicated at 140. These serve as a
cathode and anode for the resulting cell or battery. FIG. 1E provides a
planar view of contact layout to minimize series resistance and simplify
packaging. The device can then be mounted in a package and interfaced
with the external world via wire-bonding.
[0021] Gaps between the pillars may be filled with radioactive fuel, such
as tritiated water (T.sub.2O), Ni-63 or other beta emitting source, such
as promethium as indicated 410 in FIG. 4. In one embodiment, a metal
radioactive source such as Ni-63 may be introduced by
electroless/electroplating or evaporation techniques. In further
embodiments, the source may be introduced before contact formation. The
package can then be sealed or left open for characterization purposes.
Aspect rations of up to 10:1 or higher, such as the entire thickness of
the wafer, may be utilized.
[0022] In a further embodiment as illustrated in FIGS. 5A and 5B, the fuel
may take the form of a fluid--liquid or gas, such as T.sub.2O or
solutions of radioactive salts. A cap 510 or container is formed on a
cell 515, such as the cell illustrated in FIGS. 1A-1E. The cap may be
formed using many different semiconductor techniques, such as PDMS, SU8,
etc. A capillary or other fill device 515 may be used to introduce the
fluid fuel into a resulting chamber 520. In further embodiments, the
fluid fuel can be introduced by injection or otherwise.
[0023] In further embodiments, a graded junction may be grown by crystal
growth techniques, such as chemical vapor deposition (CVD) or implemented
by diffusion from solid or gaseous sources on a planar semiconductor
substrate, or by ion implantation as described below. The graded junction
can then be etched to form high aspect ratio junctions. Batteries with
power density of .about.5 mW/cm2 over a period of 20 years may be
obtained. These may be useful to power sensors in low accessibility
areas, such as pacemakers, sensor nodes in bridges, tags in freight
containers and many other applications.
[0024] In one embodiment, the pillars are approximately 1 um in width,
with approximately 1 um between them. They may be 5 um to 500 um deep, or
deeper, depending on the thickness of the substrate. The dimensions may
vary significantly, and may also be a function of the self-absorption
depth in the radiation source and the penetration depth in the
semiconductor respectively.
[0025] In one embodiment, the semiconductor comprise silicon carbide
(SiC), which is suitable for use in harsh conditions due to temperature
stability, high thermal conductivity, radiation hardness and good
electronic mobility. The wide bandgap of 4H hexagonal polytype (3.3 eV)
provides very low leakage currents.
[0026] In one embodiment, SiC pillars are formed of n-type SiC. P type
dopant, such a boron is performed from a borosilicate glass boron source
formed on the pillars. The borosilicate glass may then be removed, such
as by immersion in hydrofluoric acid followed by a deionized water rinse
or by plasma etch. Both substitutional and vacancy mediated diffusion
occurs. The doping results in shallow planar p-n junctions in SiC. Doping
levels in one embodiment are approximately 1.times.10.sup.15 cm.sup.-3
for the n-type doping, and approximately 1.times.10.sup.17 cm.sup.-3 for
the p-type doping. These doping densities may vary significantly in
further embodiments. In still further embodiments, the pillars may cover
substantially the entire wafer. At current densities of approximately 3
nanoamps/cm.sup.2, they may be used to form batteries with significant
power capabilities. In still further embodiments, the pillars may be
p-type and the dopant formed on the pillars may be n-type to form
junctions.
[0027] In one example, a dopant glass, such as Borosilicate glass, PSG,
BPSG, etc., is deposited on the SiC pillars and annealed at high
temperature, such as .about.1600.degree. C. or greater than approximately
1300.degree. C. to drive in the dopants. This process may also be used on
any type of SiC structure, including planar substrates for circuit
formation. The presence of the glass on the surface, and lower
temperature than diffusing from vapor sources, reduces the effect of
surface roughening through sublimation. For short diffusions,
decomposition of the borosilicate glass appears to be minimal, as is
surface roughening of the SiC. The resulting SiC surfaces may be smooth.
[0028] In further embodiments as illustrated in FIGS. 6A, 6B, and 6C, a
SiC substrate 600, which may or may not contain structures, is used as a
starting point. Dopant glass 610, either p or n-type may be deposited on
the SiC either by chemical vapor deposition or spin-on glass methods
among other methods. The glass coated SiC is then annealed, either in
vacuum or an ambient to diffuse the boron into the SiC as represented at
620, from approximately 1300.degree. C. to approximately 1800.degree. C.
The glass 610 may then be removed by immersion in hydrofluoric acid
followed by a deionized water rinse or by a plasma etch.
[0029] In a further embodiment, dopant containing glass can be deposited
on the SiC using a plasma enhanced chemical vapor deposition (PECVD). It
may then be annealed in a vacuum at approximately greater than
1300.degree. C. and removed by immersion in hydrofluoric acid followed by
a deionized water rinse or by a plasma etch. Other boron sources, such as
boron nitride or any other boron-containing ceramic may be used in place
of the borosilicate glass to obtain p-type doping.
[0030] It should be noted that glass was originally believed to be
unstable at such high temperatures based on Si data. However, on SiC, it
remains stable enough for this sacrificial application. Temperatures
below 1300.degree. C. may provide some drive in of dopants, and may be
included in the phrase approximately greater than in some embodiments.
[0031] FIGS. 7A, 7B, 7C, and 7D illustrate formation of a pn junction by
ion implantation. A SiC substrate 710 in FIG. 7A is implanted with dopant
715, such as boron. Other p and n-type dopants may also be used. A glass
720 is then deposited on top of the implanted substrate as seen in FIG.
7B. An activation anneal is performed as illustrated in FIG. 7C, to
activate the dopant, such as by ensuring dopants achieve proper locations
within the crystalline lattice structure of the SiC. In FIG. 7D, the
glass may be removed by acid, such as HF, or plasma etch.
[0032] In one embodiment, the boron doped SiC forms a betavoltaic cell as
described above. 4H SiC may be used in one embodiment. The p-n diode
structure may be used to collect the charge from a 1 mCi Ni-63 source
located between the pillars. The following results are provided for
example only and may vary significantly dependent upon the actual
structure used. An open circuit voltage of 0.72V and a short circuit
current density of 16 nA/cm.sup.2 were measured in a single p-n junction.
An efficiency of 5.76% was obtained. A simple photovoltaic-type model was
used to explain the results. Fill factor and backscattering effects were
included in the efficiency calculation. The performance of the device may
be limited by edge recombination.
[0033] Silicon carbide (SiC) is a wide bandgap semiconductor that has been
used for high power applications in harsh conditions due to its
temperature stability, high thermal conductivity, radiation hardness and
good electronic mobility. The wide bandgap of the 4H hexagonal polytype
(3.3 eV) provides very low leakage currents. This is advantageous for
extremely low power applications. The availability of good quality
substrates, along with recent advances in bulk and epitaxial growth
technology, allow full exploitation of the properties of SiC.
[0034] Radioactive isotopes emitting I-radiation such as Ni-63 and tritium
(H-3) have been used as fuel for low power batteries. The long half-lives
of these isotopes, their insensitivity to climate, and relatively benign
nature make them very attractive candidates for nano-power sources.
[0035] The radiation hardness of SiC.sup.4 ensures the long-term stability
of a radiation cell fabricated from it. A 4H SiC p-n diode may be used as
a betavoltaic radiation cell. Due to its wide bandgap, the expected open
circuit voltage and thus realizable efficiency are higher than in
alternative materials such as silicon.
[0036] The operation of a radiation cell is very similar to that of a
solar cell. Electron-hole (e-h) pairs are generated by high-energy
.beta.-particles instead of photons. These generated carriers are then
collected in and around the depletion region of a diode and give rise to
usable power. The dynamics of high-energy electron stopping in
semiconductors are well known, with about 1/3 of the total energy of the
radiation generating usable power through the creation of electron hole
pairs. The remaining energy is lost through phonon interactions and
X-rays. A mean "e-h pair creation energy or effective ionization
parameter" in a semiconductor, takes into account all possible loss
mechanisms in the bulk for an incident high-energy electron. This e-h
pair creation energy is treated as independent of the incident electron
energy. The effective ionization energy was calculated to be 8.4 eV for
4H SiC.sup.5.
[0037] In one embodiment, doping values of 10.sup.16 cm.sup.-3 and 100%
charge collection efficiency (CCE) were assumed. Calculations were
performed for a 4 mCi/cm.sup.2 nickel-63 radiation source corresponding
to an ideal incident .beta.-electron current density of 20 pA/cm.sup.2,
which was the source used in this work. Backscattering losses and fill
factor effects are included in these calculations. The expected
performance for ideal junctions (ideality factor n=1) is compared with
junctions where current transport is dominated by depletion and/or edge
and surface recombination (n=2). The performances realized in SiC in this
work and in silicon previously are compared below.
[0038] A p+4H SiC <0001> substrate cut 8.degree. off-axis purchased
from Cree Inc. was used in this study. A 4 .mu.m thick active p layer
background doped at 3.times.10.sup.15 cm.sup.-3, followed by a 0.25 .mu.m
thick n layer nitrogen doped at 2.times.10.sup.18 cm.sup.3, were grown by
chemical vapor deposition (CVD) at 1600.degree. C. and 200 Torr at a
nominal growth rate of 2.5 .mu.m/hr. Silane and propane were used as
precursors with hydrogen as the carrier gas. The thickness of the active
layer was chosen to match the average penetration depth of
.beta.-electrons from Ni-63 (which is about 3 .mu.m), in order to provide
good charge collection. All doping levels were experimentally determined
by capacitance-voltage measurements.
[0039] Test diodes (500.times.500 .mu.m.sup.2) were patterned by
photolithography and isolated by electron cyclotron resonance (ECR)
etching in chlorine (Cl.sub.2). Backside Al/Ti contacts were evaporated
by an electron beam in vacuum. They were then annealed at 980.degree. C.
to render them ohmic. 50.times.50 .mu.M.sup.2 nickel contacts occupying
only 1% of the active device area were then patterned and annealed at
980.degree. C. in order to minimize backscattering losses from the high Z
metal.
[0040] A LEO DSM982 scanning electron microscope (SEM) at an accelerating
voltage of 17 kV (corresponding to the mean energy of .beta.-electrons
from Ni-63) and a current of 0.72 nA was used to simulate an intense
radiation source. An electrical feed-through connected to a probe tip was
used to contact the isolated devices. The substrate was contacted to the
stage with copper tape. The incident beam current density was varied by
running the SEM in TV mode and changing the effective illumination area
with constant beam current. The open circuit voltage (Voc) and short
circuit current (Isc) were measured as a function of the incident beam
current density J.sub.beam.
[0041] In separate measurements, a 1 mCi Ni-63 source placed 6 mm from the
devices was used to test the cell in air. The measured output current
density of the source was 6 pA/cm.sup.2. The output of the cell was
monitored for a period of one week.
[0042] The leakage currents of the diodes were extracted from the forward
active region of the current voltage (IV) characteristic. A typical value
of the leakage current was J.sub.0=10.sup.-12 A/cm.sup.2 with an ideality
factor of n=3 for 500 .mu.m square diodes. The n=3 behavior is believed
to be an artifact from high resistance contacts. A few of the diodes
exhibited leakage currents of .about.10.sup.-17 A/cm.sup.2 with an
ideality of n=2. The diodes were uniform in their characteristics, with
the exception of those exhibiting n=2 behavior.
[0043] Voc and Jsc are connected by the well-known photovoltaic relation
derived from the diode equation with constant electron-hole pair
generation, Voc = nV th .times. ln .function. ( Jsc J 0 )
.times. .times. for .times. .times. Jsc J 0 ( 1 )
where J.sub.0 is the reverse leakage current density of the diode,
V.sub.th is the thermal voltage and n is the ideality factor. The voltage
thus calculated from equation (1) using the measured value of J.sub.0 is
0.76 V for the Ni-63 source. There is good agreement between the open
circuit voltage extracted from the above equation and the 0.72 V measured
under .beta.-electron illumination. Furthermore, the dependence of Voc on
the illumination current density also exhibits an ideality of n=3,
suggesting that the betavoltaic cell does indeed function in a manner
analogous to a photovoltaic cell. The radiation cell was thus modeled
with the following simple equation for a 500.times.500 .mu.m.sup.2 diode:
P = .times. IV = .times. I 0 .function. ( exp
.function. ( V nV th ) - 1 ) .times. V - IscV .apprxeq.
.times. I 0 ( exp .times. ( V nV th ) .times. V - IscV
.times. .times. .times. for .times. .times. Isc I 0
( 2 ) where P is the power obtained from the cell. We have used
I.sub.0=(25.times.10.sup.-4)(1.times.10.sup.-12)A, n=3 and
Isc=(25.times.10.sup.-4)(16.times.10.sup.-9) A for one example device.
Series resistance is neglected in equation (2) as the currents being
dealt with are so low.
[0044] The current multiplication factor under monochromatic electron
illumination is .about.1000, which is less than the total 2000 predicted
by Klein's model. This is believed to stem from surface recombination, an
effect well documented for SiC diodes. It was observed that when the
illumination area was far from the edges of the diode, confined to its
center, the current multiplication factor was .about.2000 vs. 1000 for
blanket illumination, indicating that edge and surface recombination play
a role in reducing collection efficiency despite the relatively large
size of the devices (500.times.500 .mu.m.sup.2). The highest efficiency
of 14.5% and a current multiplication factor of .about.2000 were observed
for an illumination area smaller than the area of the diode. It is thus
expected that surface passivation techniques may improve the efficiency
of the cell.
[0045] Under Ni-63 irradiation, however, an enhancement in current
multiplication to .about.2400 was observed. This is believed to stem from
the details of the distribution characteristics of the .beta.-radiation
compared with monochromatic SEM electron illumination. No change in the
open circuit voltage or short circuit current was observed during the
one-week monitoring period, indicating that radiation damage did not
occur over that time. This is consistent with the radiation damage
threshold in SiC.sup.4.
[0046] The overall efficiency of the radiation cell may be computed from
Efficiency = FF .times. VocJsc V mean .times. J beam
.times. .times. where ( 3 ) FF = V p .times. J p
VocJsc ( 4 )
[0047] where V.sub.p and J.sub.p are the voltage and current density at
the maximum power point, respectively. These were calculated numerically
from equation (2) or directly from the measured data in FIG. 2c).
V.sub.mean=17 kV corresponds to the average energy of a .beta.-particle
from Ni-63 (17 keV) and J.sub.beam is the current density from the
radiation source or from the SEM. Table 1 shows a comparison of the
values of various salient parameters obtained by measurement and
extraction from the model in equation (2). Fairly good correspondence is
seen with the model despite the fact that the Ni-63 irradiation
measurement was performed in air, implying that our model is an adequate
first order description of the radiation cell. The discrepancy of the
fill factor at the low currents from Ni-63 is believed to have arisen
from suboptimal tunneling contacts. The measured fill factors approached
their ideal values at currents>80 nA/cm.sup.2.
TABLE-US-00001
TABLE 1
Parameter Measured Model
J.sub.0 (A/cm.sup.2) .sup. 1 .times. 10.sup.-12 Used measured value
n 3 Used measured value
Jsc (A/cm.sup.2) 1.6 .times. 10.sup.-8 Used measured value
Voc (V) 0.72 0.76
Vp (V) 0.60 0.60
Jp (A/cm.sup.2) 0.98 .times. 10.sup.-8 1.38 .times. 10.sup.-8
FF 0.51 0.68
[0048] Despite the low currents from the Ni-63 source, devices were
obtained with a voltage of 0.72V and an efficiency of 5.76%, which can be
used directly in circuits. By comparison, the use of silicon, which gives
much lower voltages (.about.100 mV.sup.3), necessitates multiple cells in
series for usable power, complicating device geometry. Leakage currents
as low as 10.sup.-24 A/cm.sup.2 have been reported for SiC PN junctions.
With leakage currents of .about.10.sup.-24 A/cm.sup.2 and n=2, one can
expect a voltage of .about.1.93 V and an efficiency of .about.13%.
[0049] The Abstract is provided to comply with 37 C.F.R. .sctn.1.72(b) to
allow the reader to quickly ascertain the nature and gist of the
technical disclosure. The Abstract is submitted with the understanding
that it will not be used to interpret or limit the scope or meaning of
the claims.
* * * * *